I am a Senior Research Scientist
in the Academy of
Sciences
of the Czech Republic, Prague. I am an Active Member of the Electrochemical
Society,
USA and have served as an Executive Committee Member and
Councillor
of its European Local Section. I have also joined the American
Chemical
Society as a Member. In 2002 I was elected as an invited
Fellow of the World Innovation Foundation (F.W.I.F.). It was also
a
great honor for me to be
an invited team leader of Czech women
physicists in the 1st, 2nd, 3rd and 4th IUPAP International
confereneces on
women
in physics in 2002 (Paris, France), 2005 (Rio de Janeiro, Brazil),
2008
(Seoul, Korea) and 2011 (S. Africa).
My name has appeared in the Marquis' Who is Who. In 2006, I became
a
nominated Member of the
International Advisory Board of Eurasia Conferences in Chemical
Sciences.
A main research field of mine
has been the
successful
interpretation
of
the
thermodynamic
properties of strong electrolytes in aqueous
solutions in terms of the earlier idea of partial dissociation
due to
Svante Arrhenius and
hydration (see: J. Electrochem Soc., vol.143, 1789, 1996 and
Electroanalysis,
vol. 18, 351, 2006). A
proper
understanding of the solution properties of strong electrolytes
is important since they play important roles in many
physico-chemical,
electrochemical,
biological, physiological, environmental, industrial and
atmospheric
processes.
Recently, I have found that the Golden ratio found
in the geometry of many spontaneous creations in the Nature,
actually
arises right in the core of atoms due to electrostatic reasons. It
plays
a direct role in the
assignment of exact ionic radii from a knowledge of the
interatomic
distances in molecules, and in the
interpretation of the lengths of the hydrogen bonds. The additivity
of
atomic and or ionic radii in bond lengths has helped to
establish the structures at the atomic level of many simple as
well as
complex inorganic, organic and
biological molecules. Some basic
papers of mine on the Golden ratio in the
theory of the hydrogen atom and in assigning ionic
radii, additivity of atomic radii in bond lengths and in hydration
bonds of ions with the oxygen and
hydrogen of water and in the lengths of the hydrogen bonds in
inorganic
and
biochemical groups, have been published in Molecular Physics, vol.
103, 877, 2005,
Chemical Physics Letters, vol. 429, 600, 2006; vol. 432, 348, 2006
and vol. 436, 287, 2007, The Open Structural Biology
Journal, vol. 2, 1, 2008 and in "Innovations
in
Chemical
Biology",
Ed:
B. Sener, Springer, 2009, ch.
12.
Most recently, I have
obtained unambigously, for the first time, the absolute
potential of the standard hydrogen electrode (which
was
arbitrarily
assumed to be
zero for the last 2 centuries). Thereby, the absolute
standard
redox
potentials
of the elements of the Periodic Table could now be
tabulated (See Electrochem. Solid-State Letters,
vol 12, 2009, F29-30; Electrochem. Soc. Trans, vol. 25, 159, 2010,
Electroanalysis, vol 22, 903, 2010).
Other fundamental new interesting results in physical chemistry, electrochemistry, solution chemistry, physics and structural chemistry/biology can be found in my full list of publications and significant results. Several full texts are available in arxiv.org. and Nature Precedings.
The foundation for my above interests in science was built upon my studies for the B.Sc. degree (major subjects: Physics, Chemistry and Mathematics) from Maharani's College for Women, Bangalore, University of Mysore (India); (now Maharani's Science College for Women, University of Bangalore), M.Sc. degree (by research) in Physical Chemistry from the Indian Institute of Science (I.I.Sc.), Bangalore (India). After a few years as a Junior and then a Senior Research Assistant at the I.I.Sc., I got an award from the Association of Commonwealth Universities, which enabled me to get my Ph.D. degree (by research) in Physical Chemistry from the University of Cambridge, UK.
My thesis for the Ph.D. degree was
on the thermogravitational
separation
in
solutions
of
electrolytes. It is this topic which
provoked
me to scrutinize the theory of strong electrolytes. I was
dissatisfied
with the complicated theory like several others and I eventually
came
to
the conclusion that the existing idea of complete dissociation had
to
be
abandoned in favor of the earlier idea of partial dissociation due
to ARRHENIUS.
During the twenty years after my Ph. D., I found gradually that
the equilibrium
properties
of solutions can be quantitatively explained by simple and
meaningful
mathematical
expressions involving hydration numbers and concentrations and
sizes of
ions and ion-pairs in the solution. The basic paper on the typical
strong
electrolyte, NaCl in aqueous solutions from "zero to saturation"
was
published
in the J. Electrochemical Society in June 1996 and further
complete
work in Electroanalysis, 2006 and all relevant publications are in
the
full
list. Through
this
work, the theory of ionic association due to Bjerrum also got a
renewed
appreciation: it can be used to calculate the mean distance of
closest
approach of ions in the solution. My webpage, Croatica Chem. Acta,
1997, Chem Listy, 1998 and Electroanalyis, 2006 contain many Tables of
data on the
actual degrees of dissociation and hydration numbers of aqueous
strong
electrolytes, which can be used for thermodynamic
calculations.
Thus, there is no need
anymore for "acitvity or osmotic coefficients",
which are
"correction factors" evaluated
based on the assumption of complete dissociation.
It was a great honor for me that my above work on the thermodynamics of aqueous strong electrolytes was recoginzed by the award of an Invitation Plenary Lecturership by the Organizing Committee of the "Symposium Svante Arrhenius" in Uppsala, in November 2003, commemorating the Centenary of the award of the Nobel Prize to Arrhenius. The full text of this Lecture is in this webpage, and with additional data in Electroanalysis, 2006. Most recently, it was an honor to be be invited by the Women Chemists Committee of the ACS for a Symposium featuring seven successful women scientists (http://www.chemistry2011.org/participate/activities/show?id=153) on the occasion of IYC 2011 celebration by the ACS in 2011. The full text of my talk with audio (with 4 of my notable scientific contributions is in the ACS website at: http://www.softconference.com/ACSchem/player.asp?PVQ=HGFE&fVQ=FIDDGM&hVQ
Personally, I consider myself very fortunate to be a scientist and I have always enjoyed both experimental and theoretical research. I feel that physico-chemical phenomena follow simple mathematical rules and therefore only as much mathematics must be used as to bring out the science governing the phenomena (- Occam's rule!). I would like also to add that if one has the talent to grasp the principles of science and mathematics, it will be a pity not to cultivate this unique gift to explore the many dark corridors in science and understand the workings of Nature. In this venture one has to take both failure and success with equal spirit, since the former contributes by showing the path to avoid.
For all what I have done so far, I am grateful to the many in India (especially to the dedicated scientist, my late grandfather Prof. P. R. Ayyar, Research Professor of Chemistry, I.I.Sc., Bangalore and to his cousin, Sir C.V. Raman, for his brilliant lectures), in Cambridge (UK) and in other places in the world which I have visited, who enabled me to cultivate the desire and enjoyment of working in Science. I am equally obliged to some scientists here (in Czech Republic) for giving me the moral support. Turning to my family, I am very fortunate to have had their loving encouragement. My special gratitude is also due to the many scientists in the world who have supported, appreciated and criticized my ideas during my several journeys abroad to many countries (USA, Canada, UK, Europe, Japan and Asia) for lectures at conferences, and seminars and talks at other Institutions: (IISC (Bangalore, India), Univ. of Pisa (Italy), Univ of Utrecht (Netherlands), Univ. of Pierre & Marie Curie (Paris), Johns Hopkins Univ., UMBC, Towson Univ, and Stevenson Univ. (all in Baltimore), NIST (Gaithersberg), MIT and Harvard Univ. (Cambridge, MA), Tufts Univ (Medford, MA), Univ. of Waterloo (Waterloo, Canada), Chemical Heritage Foundation (Philadelphia), Sofia Univ. and Univ of Kyoto (Japan), Univs.of Regensburg, Aachen and Dresden, Hahn Meittner Inst., Berlin (all in Germany), Univ. of Uppsala (Sweden), and a few others.
I have enjoyed traveling and exploring
many
countries and notably exotic amongst them was a trip which I
undertook
after
seeing the fascinating paintings and photos of the arctic scenery
in
the Scott Polar Research Institute (http://www.spri.cam.ac.uk/),
next
door
to
our
Lensfield
Road
Chemical
Labs.
in
Cambridge. It was a 20-day
trip by boat
from
England (in August 1967, ) to
the land of the midnight Sun, Spitzbergen (video in:
http://www.cruisenorway.com/spitsbergen):
(by
'Jupiter'
from
Newcastle
at
55oN to Bergen at 60oN
and
back)
along the
Norwegian coast (by 'Nordstjernen' from Bergen to Tromso at 69oN
and
back
from
Tromso
to
Bergen
by
'Ragnvaldjarl',
from
Tromso to Spitzbergen (~ 76oN - 81oN
and
back
(by
a
small
postal school boat: 'Skule' which went once a
month), stopping at Bjornoya (at ~ 74.5oN),
and reaching
upto 80.2oN
(http://en.wikipedia.org/wiki/File:Topographic_map_of_Svalbard.svg)
in
open
sea
above
the
northern
tip
in
Spitzbergen.
I
visited
(in Norway) the many picturesque coastal
towns and the Lofotens and (in Spitzbergen) Longyear Byen (capital
at
~78oN; after disembarking from the boat I saw coming in
front of us, the famous polar bear hunter, Hilmar Nois!), Ny
Alesund
(at 79oN, Amundsen and others' base for their
expedition to
the
North Pole), Kongs fjord,
Lilliehook fjord, Virgohamn (see:
http://www.sysselmannen.no/hovedEnkel.aspx?m=45275),
(Andre's
base
at
~79.8oN, for the balloon expedition
in
1896/1897 to the North
Pole, with Svante Arrhenius as
the
hydrogarpher)
and
many
other
interesting
fjords,
lakes,
bird
cliffs
and glaciers. This trip turned out to be
more adventurous
by my losing at Tromso, before embarking 'Skule', my baggage with
all
my equipment, except my
handbag with my cheque book etc. and my camera, and learning
later by a telegram for me received at the
World's northernmost postoffice at Ny Alesund that the suitcase
will be
waiting
for me at Tromso on
my return journey!