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Grants

TOPIC: Molecular Electrochemistry.

Electrochemistry of nano-structures at heterogeneous interfaces: Formation, properties and electron transfer reactions.

2004-2006

No. COST 1P04 OCD 15.10, Ministry of Education, Youth and Sports of the Czech Republic

Abstract:
Research of redox reaction of organic and organometallic compounds that form isolated and organized structures at the interface solution-metallic electrode. Formation of inclusion complexes of the type host-guest inside cavities of cyclodextrins.Mechanism of redox activation inside cavities of cyclodextrins. Mechanism of electron transfer by means of through bonds and through space. Electronic communication of redox centers. Mechanism of nucleation and growth of monomolecular and multilayer films. In situ detection of redox intermediates. Electrode impedance for analysis of film formation. Quantum chemical interpretation of redox reactions.

    doc. RNDr. POSPĂŤĹ IL LubomĂ­r, CSc.

    Department: Department of Electrochemistry at the Nanoscale
    Phone: (+420) 26605 3197
    Fax: (+420) 286582307
    E-mail: lubomir.pospisilatjh-inst.cas.cz
    WWW: http://www.jh-inst.cas.cz/~pospisil/
    Room: 507


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